
Journal of the Chemical Society, Dalton Transactions p. 1515 - 1519 (1981)
Update date:2022-08-06
Topics:
Briant, Clive E.
Rowland, Keith A.
Webber, Craig T.
Mingos, D. Michael P.
The potential of a one-electron oxidising agent in organometallic chemistry has been evaluated.In complementary redox reactions with metallocenes, salts of the general from a cell of dimensions a = 12.218(2), b = 13.187(2), c = 17.832(2) Angstroem, β = 91.80(1) deg and Z = 4, the final R and R' being 0.046 and 0.051 respectively based on full-matrix refinement of 167 variables and 4273 observations.This structural determination confirms that (3) contains an octahedral iridium(III) unit linked to a square-planar palladium fragment by means of chloride bridges.
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Doi:10.1021/jo00337a010
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