CATALYTIC TRANSFER HYDROGENATION BY CATIONIC RHODIUM(I) COMPLEXES

DOI: 10.1016/S0022-328X(81)80014-9

Source and publish data:

Journal of Organometallic Chemistry p. 399 - 404 (1981)

Update date:2022-08-05

Topics:

Authors:

Uson, R.

Oro, L. A.

Sariego, R.

Esteruelas, M. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(81)80014-9

Complexes formed by adding Group Vb ligands to ClO4 in the presence of potassium hydroxide catalyze hydrogen transfer from isopropanol to acetophenone, cyclohexene and other unsaturated substrates.The catalytic activity depends upon the nature of the mono- or bidentate nitrogen- or phosphorus-donor ligands. 2>ClO4 catalyses the selective reduction of hexyne or diolefins.

Full text of DOI:10.1016/S0022-328X(81)80014-9

Products guided by the article

Product name:C₇H₈Rh(C₆H₅)2PCHCHP(C₆H₅)2⁽¹⁺⁾*ClO₄^(1-)={RhC₇H₈(CH)2(P(C₆H₅)2)2}{ClO₄}

Cas No:79170-25-5

R&D Labs maybe for 79170-25-5

SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district

Relevant to this article

HYDROGEN BONDED COMPLEX-II; THE LACTAM-PHENOL RATIOS AND STRUCTURES IN LACTAM-PHENOL COMPLEXES

Doi:10.1016/S0040-4020(01)98928-8
(1981)
Studies on ketene and its derivatives. CV. Photoreaction of diketene with sec-alcohols

Doi:10.1248/cpb.29.1624
(1981)
ELEKTROCHEMISCHE REDUKTIVE ALKYLIERUNG VON α,β-UNGESAETTIGTEN CARBONYLVERBINDUNGEN

Doi:10.1016/S0040-4039(01)81799-8
(1981)
Synthesis of the tubuvaline-tubuphenylalanine (Tuv-Tup) fragment of tubulysin

Doi:10.1021/ol048252i
(2004)
Application of a catalytic palladium biaryl synthesis reaction, via C-H functionalization, to the total synthesis of Amaryllidaceae alkaloids

Doi:10.1016/j.tet.2004.08.030
(2004)
Solvolytic Studies of the Highly Deactivated 1-Aryl-1-(trifluoromethyl)ethyl Tosylates

Doi:10.1021/ja00365a038
(1982)

Article Doi