Journal of the Chemical Society. Perkin transactions I p. 2363 - 2367 (1981)
Update date:2022-08-04
Barton, Derek H. R.
Motherwell, Robyn S. Hay
Motherwell, William B.
Tri-n-butyltin hydride reduction of an αβ-epoxy-O-thiocarbonylimidazolide derivative of an alcohol leads via oxiran ring-opening to the formation of an allylic alkoxyl radical.By a suitable choice of experimental conditions, this radical can either be quenched by hydrogen-atom transfer from the stannane or allowed to undergo further rearrangement.
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Doi:10.1016/0040-4020(82)85076-X
(1982)Doi:10.1039/DT9810001753
(1981)Doi:10.1246/bcsj.77.1703
(2004)Doi:10.1016/S0008-6215(00)85599-8
(1981)Doi:10.1021/jo049880g
(2004)Doi:10.1002/hlca.19860690306
(1986)
