Tetrahedron Letters p. 2291 - 2294 (1981)
Update date:2022-08-03
Topics:
Torii, Sigeru
Uneyama, Kenji
Nakai, Toshiyuki
Yasuda, Tsuneo
The chlorinative ene-type reaction of isoprenoids (1<*>2) has been performed by electrolysis in CH2Cl2-H2O-NaCl system.The reaction provides useful allylic chlorides 2 for terpene synthesis in high yields and is affected strikingly by the nature of halide ions and solvents. dl-Theaspirane 21 was prepared from α-dihydroionol via the electrolysis.
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Doi:10.1007/BF00503665
(1981)Doi:10.1016/S0022-328X(00)82889-2
(1980)Doi:10.1016/S0020-1693(00)81897-6
(1982)Doi:10.1016/j.molstruc.2013.07.031
(2013)Doi:10.1021/om049395b
(2004)Doi:10.1002/chem.201703453
(2017)
