Reactions and Properties of Some Trimethyleneplatinum(IV) Complexes. Part 11. Platinacyclobutanes derived from Methylcyclopropane

DOI: 10.1039/DT9810001738

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1738 - 1745 (1981)

Update date:2022-08-04

Topics:

Authors:

Al-Essa, Razak J.

Puddephatt, Richard J.

Perkins, Duncan C. L.

Rendle, Melvyn C.

Tipper, Charles F. H.

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Article abstract of DOI:10.1039/DT9810001738

It is shown that platinacyclobutanes derived from methylcyclopropane exist as a mixture of isomers with partial structures PtCH2CHMeCH2 and PtCH2CH2CHMe, and that these isomers interconvert easily.In some cases decomposition of these platinacyclobutanes gives ylide complexes L>, e.g.L = 2-methylpyridine, while in other cases but-1-ene complexes , e.g.L = CD3CN, are formed.In both cases the products are formed selectively from the least stable isomer of the platinacyclobutane.At higher temperatures or on photolysis, platinacyclobutane complexes such as decompose to give but-1-ene, 2-methylpropene, propene, and ethylene and the relative yields depend on the experimental conditions.Possible mechanisms are discussed.

Full text of DOI:10.1039/DT9810001738

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