REACTION OF exo-2-NORBORNYL AND 1-ADAMANTYL p-TOLUENESULFONATES WITH SODIUM PHENOXIDE IN TETRAHYDROFORAN. IONIZATION OF THE SUBSTRATES UNDER "APPARENTLY-SN2" CONDITIONS

DOI: 10.1246/cl.1981.935

Source and publish data:

Chemistry Letters p. 935 - 938 (1981)

Update date:2022-08-04

Topics:

Authors:

Takeuchi, Ken'ichi

Kato,Yukari

Moriyama, Takamasa

Okamoto, Kunio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.935

exo-2-Norbornyl and 1-adamantyl tosylates react with sodium phenoxide in tetrahydrofuran via ionization, most probably through a cyclic transition state.The results call for attention in interpreting substitution reactions under "apperently-S_N2" conditions.

Full text of DOI:10.1246/cl.1981.935

Products guided by the article

Product name:1-(4-phenoxybutoxy) adamantane

Cas No:79621-74-2

R&D Labs maybe for 79621-74-2

HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI

Relevant to this article

PURIFICATION OF 2,5-ANHYDRO-D-HEXITOL BIS(PHOSPHATES) AND IDENTIFICATION OF A MAJOR 1,4,6-TRIS(PHOSPHATE) CONTAMINANT BY (31)P-, (13)C-, AND (1)H-N.M.R. SPECTROSCOPY

Doi:10.1016/S0008-6215(00)85572-X
(1981)
Regioselective ortho-Acylation of N-Aryl-1,2,3-triazoles with Alcohols in Water

Doi:10.1002/ejoc.201600479
(2016)
4-Hydroxyquinoline-3-carboxylic acids as inhibitors of cell respiration. 2. Quantitative structure-activity relationship of dehydrogenase enzyme and Ehrlich ascites tumor cell inhibitions

Doi:10.1021/jm00343a011
(1982)
Domino Strategy for the Stereoselective Construction of Angularly Fused Tricyclic Ethers

Doi:10.1021/acs.joc.5b02241
(2015)
A New Photochemical Spiroannelation Method. Access to Substituted Spirocyclohexanepiperidines

Doi:10.1039/c39810000832
(1981)
Doi:10.1021/jo01349a033
(1966)

Article Doi