REACTION OF exo-2-NORBORNYL AND 1-ADAMANTYL p-TOLUENESULFONATES WITH SODIUM PHENOXIDE IN TETRAHYDROFORAN. IONIZATION OF THE SUBSTRATES UNDER "APPARENTLY-SN2" CONDITIONS

DOI: 10.1246/cl.1981.935

Source and publish data:

Chemistry Letters p. 935 - 938 (1981)

Update date:2022-08-04

Topics:

Authors:

Takeuchi, Ken'ichi

Kato,Yukari

Moriyama, Takamasa

Okamoto, Kunio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.935

exo-2-Norbornyl and 1-adamantyl tosylates react with sodium phenoxide in tetrahydrofuran via ionization, most probably through a cyclic transition state.The results call for attention in interpreting substitution reactions under "apperently-S_N2" conditions.

Full text of DOI:10.1246/cl.1981.935

Products guided by the article

Product name:1-(4-phenoxybutoxy) adamantane

Cas No:79621-74-2

R&D Labs maybe for 79621-74-2

PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Weifang Adde Economic And Trade Co.,LTD.

Contact:86-536-8885548

Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Cerametek Materials（ShenZhen）Co., Ltd.

Contact:+86-755-2324.2554

Address:A3-#9, YongChuan Street, Suite 501
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China

Relevant to this article

PURIFICATION OF 2,5-ANHYDRO-D-HEXITOL BIS(PHOSPHATES) AND IDENTIFICATION OF A MAJOR 1,4,6-TRIS(PHOSPHATE) CONTAMINANT BY (31)P-, (13)C-, AND (1)H-N.M.R. SPECTROSCOPY

Doi:10.1016/S0008-6215(00)85572-X
(1981)
Regioselective ortho-Acylation of N-Aryl-1,2,3-triazoles with Alcohols in Water

Doi:10.1002/ejoc.201600479
(2016)
4-Hydroxyquinoline-3-carboxylic acids as inhibitors of cell respiration. 2. Quantitative structure-activity relationship of dehydrogenase enzyme and Ehrlich ascites tumor cell inhibitions

Doi:10.1021/jm00343a011
(1982)
Domino Strategy for the Stereoselective Construction of Angularly Fused Tricyclic Ethers

Doi:10.1021/acs.joc.5b02241
(2015)
A New Photochemical Spiroannelation Method. Access to Substituted Spirocyclohexanepiperidines

Doi:10.1039/c39810000832
(1981)
Doi:10.1021/jo01349a033
(1966)

Article Doi