Ultrasound in Lipids. Furan Formation under Ultrasonic assisted Simmons-Smith Reaction and the Effect of Cadmium and Copper as Zinc Replacers

DOI: 10.1039/C39870001460

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Journal of the Chemical Society. Chemical communications p. 1460 - 1461 (1987)

Update date:2022-08-06

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Authors:

Lie, Marcel S. F.

Jie, Ken

Lam, Wilson L. K.

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Article abstract of DOI:10.1039/C39870001460

Methyl 12-oxo-octadec-9-cis-enoate gave methyl 9,12-epoxyoctadeca-9,11-dienoate when treated with zinc or cadmium in the presence of di-iodomethane and 1,2-dimethoxyethane under concomitant ultrasonic irradiation, while under similar conditions copper caused cyclopropanation across the ethylenic bond in methyl oleate and ricinoleate.

Full text of DOI:10.1039/C39870001460

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