Journal of the Chemical Society. Perkin transactions I p. 2677 - 2679 (1981)
Update date:2022-08-05
Topics:
Bruce, J. Malcolm
Roshan-Ali, Yusuf
Electron-releasing substituents at the 3-position of allyl phenyl ethers favour Claisen rearangement of the allyl group to the 6-position, whereas electron-acceptors favour migration to the 2-position. 2-Acylhydroquinone 4-allyl ethers yield, predominantly, the 3-allyl isomers, probably because internal hydrogen bonding confers naphthalenoid character on the aryl residue.
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(1981)
