SYNTHESIS OF 2,2,2-TRICHLOROETHYL 3,6-DI-O-BENZYL-2-DEOXY-2-PHTHALIMIDO-β-D-GLUCOPYRANOSIDE, AND ITS REACTION WITH GLYCOSYL HALIDES

Article abstract of DOI:10.1016/S0008-6215(00)84692-3

2,2,2-Trichloroethyl 3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside (9) was synthesized in 6 steps from the readily available 1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose in 25 percent overall yield by employing the stannyl me