Journal of Organic Chemistry p. 1799 - 1807 (1982)
Update date:2022-07-30
Topics:
Lewin, Anita H.
Whaley, M. Glenn
Parker, Steven R.
Carroll, F. Ivy
Four isomeric 12-carboxyretinoic acids and their dimethyl esters (trans, 13-cis, 11-cis, and 11-cis,13-cis), along with two isomeric retinoic anhydrides (13-cis and 11-cis,13-cis), have been prepared and fully characterized.The primary product of the base-promoted condensation of trans-(β-ionylidene)acetaldehyde and β-methylglutaconate has been shown to be the 11-cis,13-cis-diacid.The interconversions and relative stabilities of these retinoids are discussed in terms of their conformations
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Doi:10.1021/jo00348a033
(1982)Doi:10.1080/00397910802527748
(2009)Doi:10.1055/s-2005-918931
(2005)Doi:10.1021/jo00345a040
(1982)Doi:10.1039/b711391a
(2007)Doi:10.1021/acs.orglett.9b01327
(2019)