Journal of the Chemical Society. Perkin transactions I p. 1819 - 1822 (1993)
Update date:2022-08-03
Topics:
Hazra, Braja G.
Pore, Vandana S.
Joshi, Padmakar L.
A streoselective synthesis of 6-oxo-23,24-dinor-5α-cholan-2α,3α,22-triyl triacetate 9 was achieved in 44percent overall yield in nine steps starting from 3β-hydroxyandrost-5-en-17-one 8.The important features of this synthesis are the modified Wittig reaction on the 17-oxo steroid 8 and the stereospecific generation of the chiral centre at C-20 by a resin-catalysed ene reaction on (Z)-3β, p-tolylsulfonyloxypregna-5,17(20)-diene 11.
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(1933)Doi:10.1071/CH9670723
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