Circular dichroism spectra of cobalt(III) and platinum(II) complexes of the tert-butyl-substituted diamine 3,3-dimethyl-1,2-butanediamine

Article abstract of DOI:10.1021/ic00133a040

The tert-butyl-substituted diamine (S)-3,3-dimethyl-1,2-butanediamine (dmbn) forms five-membered chelate rings with metals that are effectively restricted to the δ conformation in which the tert-butyl group is equatorial. The absorption and circular dichr