Interconversion of Cembranolide &δ- and &γ-Lactones: Synthesis of the C-1 Epimer of Isolobophytolide

DOI: 10.1021/jo00343a019

Source and publish data:

Journal of Organic Chemistry p. 699 - 701 (1982)

Update date:2022-08-05

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Authors:

Marshall, James A.

Karas, Lawrence J.

Coghlan, Michael J.

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Article abstract of DOI:10.1021/jo00343a019

The δ-lactone cembranolide diterpene crassin alcohol (2) has been converted to an isomeric γ-lactone isocrassin alcohol (6) by a sequence involving kinetically controlled addition of benzenethiol to the conjugated lactone double bond followed by base-prom

Full text of DOI:10.1021/jo00343a019

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