Interconversion of Cembranolide &δ- and &γ-Lactones: Synthesis of the C-1 Epimer of Isolobophytolide

DOI: 10.1021/jo00343a019

Source and publish data:

Journal of Organic Chemistry p. 699 - 701 (1982)

Update date:2022-08-05

Topics:

Authors:

Marshall, James A.

Karas, Lawrence J.

Coghlan, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00343a019

The δ-lactone cembranolide diterpene crassin alcohol (2) has been converted to an isomeric γ-lactone isocrassin alcohol (6) by a sequence involving kinetically controlled addition of benzenethiol to the conjugated lactone double bond followed by base-prom

Full text of DOI:10.1021/jo00343a019

Products guided by the article

Product name:(9E)-6-hydroxy-6,10,14-trimethyl-3-methylidene-2-oxo-2,3,3a,4,5,6,7,8,11,12,15,15a-dodecahydrocyclotetradeca[b]furan-5-yl acetate

Cas No:80375-67-3

R&D Labs maybe for 80375-67-3

Xi'an Herbland Tech Inc.

Contact:+86-29-88710656

Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Jiangsu Wanlong Chemical Co., Ltd.

website:http://www.wanlongchem.com

Contact:+86-511-86810993 0086-511-8681 0888;

Address:Quanzhou Town, Danyang City, Jiangsu
Hangzhou Maytime Bio-Tech Co.,Ltd.

website:http://www.maytime.com.cn

Contact:+86-571-88925295 88920965

Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
SHANXI XINTIANYUAN PHARMACEUTICAL CO., LTD.

website:http://www.tychemical.com

Contact:0086-358-3521713 3521715

Address:No. 1 Yintong Road, Shanxi Jiaocheng Economic Development Zone, Xiajiaying Town, Jiaocheng County, Lvliang City, Shanxi Province, China

Relevant to this article

NEW INTRAMOLECULAR EXCIPLEXES BETWEEN POLYNUCLEAR AROMATIC HYDROCARBONS AND HEAD-TO-HEAD VS HEAD-TO-TAIL PHOTODIMERIZATION OF MONOSUBSTITUTED ANTHRACENES

Doi:10.1016/S0040-4039(01)81949-3
(1981)
Singlet oxygen oxidation of pyrroles: Synthesis and chemical transformations of novel 4,4-bis(trifluoromethyl)imidazoline analogs

Doi:10.1016/0040-4020(96)00578-9
(1996)
Dehydrooligopeptides. I. The facile coupling of α-amino acids with α-dehydroamino acids to dehydrodipeptides

Doi:10.1246/bcsj.53.2905
(1980)
2-ACYLCYCLOBUTANONES FROM α-CYCLOPROPYLIDENE KETONES

Doi:10.1246/cl.1981.1515
(1981)
A stereoselective synthesis of the C(1)-C(16) fragment of the bryostatins

Doi:10.1016/j.tetlet.2004.09.124
(2004)
Synthesis and Opto-electronic Properties of BODIPY o-OPhos Systems

Doi:10.1111/php.13306
(2020)

Article Doi