Tetrahedron Letters p. 3043 - 3046 (1981)
Update date:2022-08-05
Topics:
Liotta, Dennis
Saindane, Manohar
Barnum, Christopher
Ensley, Harry
Balakrishnan, Pattabiraman
A variety of β-dicarbonyl compounds can be converted to the corresponding unsaturated derivatives in high yields.The process involves reaction of the β-dicarbonyl carbanion with Se metal, followed by alkylation with methyl iodide to form the methylseleno derivative and subsequent oxidative elimination.
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