CONJUGATE REDUCTION OF QUINONE DERIVATIVES. A ROUTE TO PHENOL KETO-TAUTOMER EQUIVALENTS

DOI: 10.1016/S0040-4039(00)97004-7

Source and publish data:

Tetrahedron Letters p. 6125 - 6128 (1990)

Update date:2022-08-05

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Authors:

Doty, Barbara J.

Morrow, Gary W.

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Article abstract of DOI:10.1016/S0040-4039(00)97004-7

1,4-Addition of hydride to quinone monoketals 1 and p-quinol ethers 2, mediated by bis-(2,6-di-t-butyl-4-methylphenoxy)-methylaluminum (MAD), affords 4,4-substituted-2-cyclohexen-1-ones 3, which represent keto-tautomer equivalents of phenols.

Full text of DOI:10.1016/S0040-4039(00)97004-7

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