5-Amino-1-vinyl-4,5-dihydro-1H-1,2,3-triazoles as a Source of 1-Amino-2-aza-1,3-butadiene

DOI: 10.1246/bcsj.54.2779

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2779 - 2785 (1981)

Update date:2022-08-04

Topics:

Authors:

Nomura, Yujiro

Takeuchi, Yoshito

Tomoda, Shuji

Ito, Masato M.

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Article abstract of DOI:10.1246/bcsj.54.2779

Thermolysis of 4,4-dimethyl-1-(1-phenylvinyl)-5-(1-pyrrolidinyl)-4,5-dihydro-1H-1,2,3-triazole gave 2-methyl-N-(1-phenylvinyl)-1-(1-pyrrolidinyl)-1-propanimine, which reacted as a 2-azabutadiene with electrondeficient dienophiles to afford the corresponding <4+2> cycloadducts.Reactivity and regioselectivity of the cycloaddition reactions were rationalized with the frontier molecular orbital treatment.

Full text of DOI:10.1246/bcsj.54.2779

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Article Doi

5-Amino-1-vinyl-4,5-dihydro-1H-1,2,3-triazoles as a Source of 1-Amino-2-aza-1,3-butadiene

DOI: 10.1246/bcsj.54.2779

Source and publish data:

Authors:

Article abstract of DOI:10.1246/bcsj.54.2779

Full text of DOI:10.1246/bcsj.54.2779

Products guided by the article

R&D Labs maybe for 80541-57-7

Relevant to this article

Divalent germanium compound with a radical-anionic ligand: Molecular structures of (dpp-BIAN)asterisk inside a circle sign-GeCl and its hydrochloration products (2) and (3) (see abstract). (dpp-BIAN = 1,2-bis{(2,6-diisopropylphenyl)imino}acenaphthene)

1,2,4-Oxadiazole derivatives of phenylalanine: potential inhibitors of substance P endopeptidase

Acetylenic carbamates. II. Reactions of 1,1-diaryl-2-propynyl carbamates with acids and bases.

Bi- and tetrametallic complexes of the noble metals with PNP-ligands

Synthesis of Novel Diphenyl Ether Herbicides

Preparation of 17α-iodoethynylandrosta- And 17α-(2-iodoethenyl) androsta-4,6-dien-17β-ol-3-ones as active site-directed photoaffinity ligands for androgen-binding proteins

Divalent germanium compound with a radical-anionic ligand: Molecular structures of (dpp-BIAN)^{asterisk inside a circle sign-}GeCl and its hydrochloration products (2) and (3) (see abstract). (dpp-BIAN = 1,2-bis{(2,6-diisopropylphenyl)imino}acenaphthene)