Journal of the Chemical Society. Chemical communications p. 1003 - 1004 (1981)
Update date:2022-08-05
Topics:
Baydar, Ahmet E.
Boyd, Gerhard V.
Lindley, Peter F.
2-Dimethylamino-5-phenyl-1,3,4-thiadiazin-6-one (2), the first representative of this ring system, undergoes thermal fragmentation to yield benzonitrile, dimethylcyanamide, and 2-dimethylamino-5-phenyl-1,3,4-thiadiazole; its reaction with 1-diethylaminopropyne results in a mixture of adducts, the 1H-pyridazin-4-one (7) and the 5H-pyridazin-4-one (10).
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