Chemistry of Heterocyclic Compounds p. 96 - 102 (1991)
Update date:2022-08-03
Topics:
Rudchenko, V. F.
Voznesenskii, V. N.
Kostyanovskii, R. G.
Evidence is presented for a synchronous mechanism of the acid-catalyzed 1,2-rearrangement of 2-methoxyisoxazolidine-2,3-dicarboxylic acid ester with migration of the ester group to the N-atom.It was shown that the reaction is suppressed in the presence of an external nucleophile or a reducing agent.The regularities found were used to explain the transformations of bicyclic systems with an -ONO-fragment.
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