Phosphinyl-Substituted Dienophiles: Their Synthesis and Directive Effects

DOI: 10.1021/jo00347a005

Source and publish data:

Journal of Organic Chemistry p. 1413 - 1416 (1982)

Update date:2022-08-06

Topics:

Authors:

Darling, Stephen D.

Brandes, Stephanie J.

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Article abstract of DOI:10.1021/jo00347a005

The unilateral directive influence of the carbonyl group in the Diels-Alder reaction can be negated by a diphenylphosphinyl group.The dienophile 4-(diphenylphosphinyl)-3-buten-2-one (4) was synthesized.Products isolated as a result of the addition of 4 to

Full text of DOI:10.1021/jo00347a005

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Product name:1-(diphenylphosphinyl)-2,3-epoxybutane

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