CHLOROETHOXY(TRIMETHYL)SILANE : A HARD-BASE TRAP WHICH PRESERVES TMS ETHER GROUPS AND IMPROVES THE WITTIG METHYLENATION OF GIBBERELLINS

DOI: 10.1016/S0040-4039(01)82090-6

Source and publish data:

Tetrahedron Letters p. 4149 - 4152 (1981)

Update date:2022-08-06

Topics:

Authors:

Mander, Lewis N.

Turner, John V.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)82090-6

A reagent, 2-chloroethoxy(trimethyl)silane (CETS), has been devised which ensures the preservation of TMS ether groups during Wittig methylenation in protic media and which makes this formerly capricious reaction with 16-keto gibberellins a reliable and straightforward procedure.

Full text of DOI:10.1016/S0040-4039(01)82090-6

Products guided by the article

Product name:C₂₇H₂₈O₆

Cas No:80994-35-0

R&D Labs maybe for 80994-35-0

CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province

Relevant to this article

Novel synthesis of L-iduronic acid using trehalose as the disaccharidic starting material

Doi:10.1016/S0040-4039(98)02662-8
(1999)
SYNTHESIS OF 4-YLIDENEBUTENOLIDES FROM 2-TRIMETHYLSILOXYFURAN

Doi:10.1016/S0040-4039(01)82929-4
(1981)
Synthesis of 5-alkyl(or aryl)pyrrolo[1,2-a]quinoxalin-4(5H)-ones by denitrocyclisation of N-alkyl(or aryl)-1-(2-nitrophenyl)-1H-pyrrole-2- carboxamides. Evidence of a Smiles rearrangement

Doi:10.1016/j.tet.2004.09.048
(2004)
FORMATION AND REACTIVITY OF DILITHIATED N-FURFURYLBENZAMIDES. SYNTHESIS OF α-SUBSTITUTED N-FURFURYLBENZAMIDES

Doi:10.1016/S0040-4039(01)93021-7
(1981)
Improved preparation of racemic 2-amino-3-(heteroaryl)propanoic acids and related compounds containing a furan or thiophene nucleus

Doi:10.1248/cpb.52.1137
(2004)
Binding two C₂ units to an electron-rich transition-metal center: The interplay of alkyne(alkynyl), bisalkynyl(hydrido), alkynyl(vinylidene), alkynyl(allene), alkynyl(olefin), and alkynyl(enyne) rhodium complexes

Doi:10.1021/om049389f
(2004)

Article Doi