CHLOROETHOXY(TRIMETHYL)SILANE : A HARD-BASE TRAP WHICH PRESERVES TMS ETHER GROUPS AND IMPROVES THE WITTIG METHYLENATION OF GIBBERELLINS

DOI: 10.1016/S0040-4039(01)82090-6

Source and publish data:

Tetrahedron Letters p. 4149 - 4152 (1981)

Update date:2022-08-06

Topics:

Authors:

Mander, Lewis N.

Turner, John V.

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Article abstract of DOI:10.1016/S0040-4039(01)82090-6

A reagent, 2-chloroethoxy(trimethyl)silane (CETS), has been devised which ensures the preservation of TMS ether groups during Wittig methylenation in protic media and which makes this formerly capricious reaction with 16-keto gibberellins a reliable and straightforward procedure.

Full text of DOI:10.1016/S0040-4039(01)82090-6

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