Reactions of Metal-Metal Multiple Bonds. 8. Forming Mo-Mo Quadruple Bonds by Reductive Elimination (Alkyl Group Disproportionation) in the Reactions of 1,2-Mo2R2(NMe2)4 Compounds (M*M) with Carbon Dioxide and 1,3-Diaryltriazines

Article abstract of DOI:10.1021/ja00372a009

Addition of CO2 and 1,3-diaryltriazines to 1,2-Mo2R2(NMe2)4 compounds (M*M), where R = CH3 and CH2Si(CH3)3, yields Mo2R2(O2CNMe2)4 and Mo2R2(NMe2)2(ArN3Ar)2 compounds, respectively, with retention of the Mo*Mo bond, whereas related reactions, where R = C2