Helvetica Chimica Acta p. 2691 - 2695 (1981)
Update date:2022-08-03
Topics:
Acemoglu, Murat von
Eschenmoser, Walter
Eugster, Conrad Hans
Optically active 5,6-epoxy-5,6-dihydro-β-ionones have been prepared for the first time and their absolute configurations were determined by correlation with (-)-(S)-α-ionone.Acid catalyzed hydrolysis of the epoxide proceeds with retention of the configuration at C(6) and with inversion at C(5).
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