Tetrahedron p. 39 - 44 (1987)
Update date:2022-08-05
Topics:
Dolbier, William R.
Al-Pekri, Dheya M.
Thermal deazetation of difluoro- and tetrafluoro-2,3-diazabicyclo<3.2.0>hept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloaddition process.A key finding was the absence of isolation of a bicyclopentane product in the difluoro case.
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