Chemistry Letters p. 9 - 12 (1982)
Update date:2022-08-04
Topics:
Inagaki, Masao
Shingaki, Tadao
Nagai, Toshikazu
The acetophenone-sensitized photolyses of benzoyl azide in cis- and trans-1,4-dimethylcyclohexanes gave the N-substituted benzamides stereospecifically.The photolyses in 2,3-dimethylbutane showed the same insertion regioselectivity ratio toward the C-H bonds as that of singlet benzoylnitrene in the direct photolysis.These facts indicate the existence of the singlet nitrene despite the triplet photosensitization and provide a chemical evidence for the establishment of a singlet-triplet equilibrium for benzoylnitrene.
View MoreTIANJIN ZHONGXIN CHEMTECH CO.,LTD.
Contact:86-022-66880623
Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Hangzhou Ocean Chemical Co., Ltd.
website:http://www.hzoceanchem.com
Contact:+86-571-88025872, 28272092, 28272096
Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Changzhou Qidi Chemical Co., Ltd
website:http://www.czqdhg.com/
Contact:86-519-83382137
Address:128-1-16# HuaYuan Street,Hutang Town,Wujin District,Changzhou City,P.R.China.
Contact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Suzhou Sibian Chemical Technology Co., Ltd
website:http://www.sibianpharm.com
Contact:+8618169181984,+8618013186906
Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Doi:10.1016/j.bmcl.2007.04.018
(2007)Doi:10.1039/P19810003020
(1981)Doi:10.1002/ardp.19823150103
(1982)Doi:10.1016/j.bmc.2010.03.036
(2010)Doi:10.1021/j100561a017
(1976)Doi:10.1002/(SICI)1099-1395(199712)10:12<879::AID-POC879>3.0.CO;2-K
(1997)
