
Chemistry Letters p. 9 - 12 (1982)
Update date:2022-08-04
Topics:
Inagaki, Masao
Shingaki, Tadao
Nagai, Toshikazu
The acetophenone-sensitized photolyses of benzoyl azide in cis- and trans-1,4-dimethylcyclohexanes gave the N-substituted benzamides stereospecifically.The photolyses in 2,3-dimethylbutane showed the same insertion regioselectivity ratio toward the C-H bonds as that of singlet benzoylnitrene in the direct photolysis.These facts indicate the existence of the singlet nitrene despite the triplet photosensitization and provide a chemical evidence for the establishment of a singlet-triplet equilibrium for benzoylnitrene.
View MoreHubei Onward Bio-Development Co., Ltd.
Contact:+86-718-8417012
Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Hangzhou innopharma technology Co,.Ltd.(expird)
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
Shenzhen Purimaxx PharmaChem Co., Ltd.
Contact:86-755-3285 0956
Address:5F, Xuxinda Industrial park, Shi yan zhou Road, Baoan District, Shenzhen, China
Hangzhou Bayee Chemical Co.,Ltd.
Contact:+86-571-86990109
Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd
Contact:0371-65771781 021-52042910
Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
Doi:10.1016/j.bmcl.2007.04.018
(2007)Doi:10.1039/P19810003020
(1981)Doi:10.1002/ardp.19823150103
(1982)Doi:10.1016/j.bmc.2010.03.036
(2010)Doi:10.1021/j100561a017
(1976)Doi:10.1002/(SICI)1099-1395(199712)10:12<879::AID-POC879>3.0.CO;2-K
(1997)