Enantioselective Generation and Diastereoselective Reactions of Chiral Enolates Derived from α-Heterosubstituted Carboxylic Acids

DOI: 10.1002/hlca.19810640829

Source and publish data:

Helvetica Chimica Acta p. 2704 - 2708 (1981)

Update date:2022-08-05

Topics: Chiral Enantioselective Diastereoselective Enolates

Authors:

Seebach, Dieter

Naef, Reto

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Article abstract of DOI:10.1002/hlca.19810640829

Dioxolanones 7 and 8a and oxazolinones 9a derived from pivalaldehyde and lactic acid, mandelic acid, and proline, respectively, furnish chiral enolates of type 3 by deprotonation with LDA.Reactions of these enolates with alkyl halides, aldehydes, and keto

Full text of DOI:10.1002/hlca.19810640829

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