Enantioselective Generation and Diastereoselective Reactions of Chiral Enolates Derived from α-Heterosubstituted Carboxylic Acids

DOI: 10.1002/hlca.19810640829

Source and publish data:

Helvetica Chimica Acta p. 2704 - 2708 (1981)

Update date:2022-08-05

Topics: Chiral Enantioselective Diastereoselective Enolates

Authors:

Seebach, Dieter

Naef, Reto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19810640829

Dioxolanones 7 and 8a and oxazolinones 9a derived from pivalaldehyde and lactic acid, mandelic acid, and proline, respectively, furnish chiral enolates of type 3 by deprotonation with LDA.Reactions of these enolates with alkyl halides, aldehydes, and keto

Full text of DOI:10.1002/hlca.19810640829

Products guided by the article

Product name:(2S,5S)-2-(t-butyl)-5-phenyl-5-propyl-1,3-dioxolan-4-one

Cas No:81037-00-5

R&D Labs maybe for 81037-00-5

Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Beyond Pharmaceutical Co., Ltd

Contact:+86-571-8195-3185

Address:No. 13-1, Liansheng Road, Yuhang District
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
ChengduChroma-BiotechCo.,Ltd.

Contact:86-28-61993785

Address:No.70-13-21, North Section, Erhuan

Relevant to this article

Nitration, Amination, and Halogenation of Di-O-methylphloracetophenone

Doi:10.1007/BF00814339
(1982)
<β-(Trimethylsilyl)ethyl>lithium: A New Reagent for Carbonyl Reductive Vinylation

Doi:10.1021/jo00349a038
(1982)
On the Chemistry of 4-Aminothiazoline-2-thiones

Doi:10.1007/BF00900005
(1981)
Phosphonosilylations of Cyclic Enones

Doi:10.1021/jo00132a062
(1982)
Further synthetic studies on rifamycin S

Doi:10.1016/S0040-4020(01)93261-2
(1981)
1,2-MONO-, 1,2:3,5-DI-, AND 1,2:5,6-DI-O-ISOPROPYLIDENE-β-L-IDOFURANOSES; AN EXAMPLE OF 1,3-DIOXOLANE-1,3-DIOXANE ISOMERISATION

Doi:10.1016/S0008-6215(00)81002-2
(1982)

Article Doi