Synthesis and X-Ray Crystal Structure Determination of the Cationic Gold Cluster Compound (NO3)2

DOI: 10.1039/c39810001218

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1218 - 1219 (1981)

Update date:2022-08-03

Topics:

Authors:

Velden, Jan W. A. van der

Bour, Jan J.

Bosman, Wil P.

Noordik, Jan H.

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Article abstract of DOI:10.1039/c39810001218

The reaction of (NO3)2 (L = PPh3) with the phosphine scavenger 2 yields (NO3)2, X-ray analysis of which reveals the Au skeleton to be a fragment of the centred icosahedron; the cluster is an intermediate in the reactions of 3+, and its 197Au Moessbauer spectrum lacks, like that of 3+, a separate resonance for the central Au atom.

Full text of DOI:10.1039/c39810001218

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