Studies of Unusual Amino Acids and Their Peptides. XIV. The Asymmetric Hydrogenation of the Phenylhydrazone of Methyl N-(3,3-Dimethyl-2-oxobutanoyl)-L-valinate

DOI: 10.1246/bcsj.55.341

Source and publish data:

Bulletin of the Chemical Society of Japan p. 341 - 342 (1982)

Update date:2022-08-05

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Authors:

Miyazawa, Toshifumi

Takashima, Katsumi

Yamada, Takashi

Kuwata, Shigeru

Watanabe, Hiroshi

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Article abstract of DOI:10.1246/bcsj.55.341

The asymmetric hydrogenation of the phenylhydrazone of methyl N-(3,3-dimethyl-2-oxobutanoyl)-L-valinate was investigated using palladium catalysts.The configuration of the newly formed t-leucine moiety was found to be L.

Full text of DOI:10.1246/bcsj.55.341

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