Synthesis of Macrocyclic Lactones by Ring Enlargement Reaction

DOI: 10.1002/hlca.19820650124

Source and publish data:

Helvetica Chimica Acta p. 249 - 251 (1982)

Update date:2022-08-04

Topics:

Authors:

Kostova, Kalina

Lorenzi-Riatsch, Annalaura

Nakashita, Yoshihiko

Hesse, Manfred

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19820650124

Treatment of 3-(1-nitro-2-oxocyclohexyl)propanal (1) prepared by Michael addition of 2-nitrocyclohexanon and acrylaldehyde with methyltri(2-propoxy)titanium yielded a mixture of 2 and 3 which was converted into 6-nitro-9-decanolide (4).

Full text of DOI:10.1002/hlca.19820650124

Products guided by the article

Product name:2-Methyl-4a-nitro-octahydro-chromen-8a-ol

Cas No:81590-77-4

R&D Labs maybe for 81590-77-4

Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Suzhou Ryan Pharmachem Technology Co.,Ltd

Contact:+86-0512-68780025

Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
Li's chemicals

Contact:+86-15850770348

Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China

Relevant to this article

HIGH-YIELDING SYNTHESES OF 4(5)-SUBSTITUTED IMIDAZOLES VIA ORGANOLITHIUM INTERMEDIATES. THE UTILITY OF SULPHONAMIDE N-PROTECTION AND SILICON-CONTAINING BLOCKING GROUPS

Doi:10.1016/S0040-4020(01)90617-9
(1986)
A new, highly efficient synthesis of conjugated nitrocycloalkenes

Doi:10.1016/S0040-4039(00)77291-1
(1994)
Double diastereoselective SuperQuat glycolate aldol reactions: Application to the asymmetric synthesis of polyfunctionalised lactones

Doi:10.1039/b411724g
(2004)
Synthesis and cytotoxic evaluation of novel platinum(II) complexes with C₂-asymmetric and C₂-symmetric chiral vicinal diamines

Doi:10.1002/cjoc.201201168
(2013)
Structure of Leucinostatin A, New Peptide Antibiotic from Paecilomyces lilacinus A-267

Doi:10.1039/c39820000094
(1982)
DEHYDRATIVE α-GLUCOSYLATION USING A MIXTURE OF p-NITROBENZENESULFONYL CHLORIDE, SILVER TRIFLUOROMETHANESULFONATE, N,N-DIMETHYLACETAMIDE, AND TRIETHYLAMINE

Doi:10.1246/cl.1982.1039
(1982)

Article Doi