Synthesis of Macrocyclic Lactones by Ring Enlargement Reaction

DOI: 10.1002/hlca.19820650124

Source and publish data:

Helvetica Chimica Acta p. 249 - 251 (1982)

Update date:2022-08-04

Topics:

Authors:

Kostova, Kalina

Lorenzi-Riatsch, Annalaura

Nakashita, Yoshihiko

Hesse, Manfred

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Article abstract of DOI:10.1002/hlca.19820650124

Treatment of 3-(1-nitro-2-oxocyclohexyl)propanal (1) prepared by Michael addition of 2-nitrocyclohexanon and acrylaldehyde with methyltri(2-propoxy)titanium yielded a mixture of 2 and 3 which was converted into 6-nitro-9-decanolide (4).

Full text of DOI:10.1002/hlca.19820650124

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