Tetrahedron p. 4195 - 4200 (1981)
Update date:2022-08-04
Topics:
Santelli-Rouvier, Christiane
By acid catalysis, gem-dihalogenocyclopropylcarbinols are converted into homoallylic α-dihalogenated cations which in general eliminate the hydrogen halide and lead to the 3-halogenopentadienyl cations from which cyclopentenones can be formed by cyclisation.For bicyclo<4.1.0>heptanes, aromatisation of the 3-halogenopentadienyl cation in benzyl bromide is observed.
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