Journal of Organic Chemistry p. 4152 - 4156 (1982)
Update date:2022-08-02
Topics:
Hoye, Thomas R.
Caruso, Andrew J.
Magee, Andrew S.
1,1-Dicarbonyl- (ester, ketone, lactone) substituted alkenes are prepared from the corresponding saturated 1-phenylsulfinyl derivatives.These are formed from precursor sulfides, which can be efficiently prepared either by oxidation of β-hydroxy-α-phenylsulfenylcarbonyl compounds or direct acylation of α-phenylsulfenyl enolate anions with acid chlorides.Some of the title compounds can be isolated and then reacted while others are generated and reacted in situ in a Diels-Alder fashion with cyclopentadiene.Endo-exo selectivities are discussed.
View MoreJi'an Hairui Natural Plant Co. Ltd.
Contact:0796-8105528
Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Contact:86-512-69362780,69362785
Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
jintan yufan Medicine Raw materials Co.,Ltd.(expird)
Contact:86-519-82808282
Address:6th,Jincheng Huangzhuang
Puyang Huicheng Electronic Material Co., Ltd
website:http://huichengchem.weba.testwebsite.cn/index_en.html
Contact:+86-393-8910800
Address:West Section Shengli Road, Puyang457000, China
Beijing Merson Pharmaceutical Co., Ltd
Contact:0086-10-80484934 0086-10-80484574/
Address:2nd Floor , No. 2 Building , No. 14 Houshayu Duan, Jingmi Road ,Shunyi District , Beijing 101318, P.R.China
Doi:10.1016/0008-6215(84)85414-2
(1984)Doi:10.1016/S0040-4020(01)97624-0
(1983)Doi:10.1016/S0040-4039(00)86858-6
(1982)Doi:10.1016/0040-4020(81)85016-8
(1981)Doi:10.1021/jo501841s
(2014)Doi:10.1021/jo0340657
(2003)
