Chemo-, Regio-, and Stereoselective Hydroalumination of 7,8-Epoxy-2,3,5,6-tetramethylenebicyclooctane

DOI: 10.1021/jo00138a022

Source and publish data:

Journal of Organic Chemistry p. 3316 - 3319 (1982)

Update date:2022-09-26

Topics:

Authors:

Gabioud, Raphy

Chapuis, Gervais

Vogel, Pierre

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Article abstract of DOI:10.1021/jo00138a022

The oxirane ring of 7,8-epoxy-2,3,5,6-tetramethylenebicyclo<2.2.2>octane (1) was not reduced by NaAlH2(OCH2CH2OCH3)2.Hydroalumination of the syn diene occured instead with the formation of a η¹-allylaluminate 5, which yielded selectively 1,2- o

Full text of DOI:10.1021/jo00138a022

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