Tetrahedron Letters p. 639 - 642 (1982)
Update date:2022-08-05
Topics:
Enders, Dieter
Lotter, Hermann
A simple and efficient 3 - step synthesis of α-dialkylamino - ketones 3 starting from aldehydes and sec.-amines is described.The unsymmetrically aminoketones are obtained as pure regioisomers via reaction of metalated α-aminonitriles 1 with aldehydes, followed by thermal HCN-elimination/tautomerization.
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Doi:10.1021/acs.joc.1c00406
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(2015)Doi:10.1021/jf020660i
(2003)Doi:10.1007/BF00506437
(1983)Doi:10.1246/bcsj.56.2527
(1983)Doi:10.1021/ja0470158
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