PALLADIUM CATALYZED SYNTHESIS OF ALLYLIC SULFONES. UTILIZATION OF α-NITRO OLEFINS AS ALLYLIC NITRO COMPOUNDS

DOI: 10.1246/cl.1985.229

Source and publish data:

Chemistry Letters p. 229 - 232 (1985)

Update date:2022-08-04

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Authors:

Tamura, Rui

Hayashi, Koji

Kakihana, Masato

Tsuji, Masanori

Oda, Daihei

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Article abstract of DOI:10.1246/cl.1985.229

α-Nitro olefins reacted with sodium benzenesulfinate in the presence of tertiary amine and palladium(0) catalyst to afford allylic sulfones.The competition experiment showed that relative rate of the sulfonylation of an α-nitro olefin to that of the corre

Full text of DOI:10.1246/cl.1985.229

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