Tetrahedron Letters p. 5877 - 5880 (1986)
Update date:2022-08-03
Topics:
Somsak, Laszlo
Batta, Gyula
Farkas, Istvan
Reductive dehalogenation of acetylated 1-bromo-D-glycosyl cyanides with tri-n-butyltin hydride favours the formation of 1,2-trans-glycosyl cyanides, while reactions with zinc-acetic acid, zinc-isopropanol, and sodium borohydride give 1,2-cis-glycosyl cyanides as the major product.
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