Donor-Atom Effects on Relative E2 Rate Constants for Reactions of Anions with Cyclohexyl Bromide

DOI: 10.1021/jo00145a053

Source and publish data:

Journal of Organic Chemistry p. 4813 - 4815 (1982)

Update date:2022-09-26

Topics:

Authors:

Bordwell, Frederick G.

Mrozack, Susan Romberg

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00145a053

2-Naphthoxide oxanions <2-NpO(1-)> and carbazole nitroanions react with cyclohexyl bromide in Me2SO solution to give cyclohexene, whereas 9-methylfluorene carbanions <9-MeFl(1-)> give substitution and benzenethiolate thianions give both elimination and substitution.The relative order of E2 rate constants for anions of the same basicity is ArS(1-) > 2-NpO(1-) > Cb(1-) > 9-MeFl(1-).

Full text of DOI:10.1021/jo00145a053

Products guided by the article

Product name:9-methyl-9-cyclohexylfluorene

Cas No:82571-47-9

R&D Labs maybe for 82571-47-9

Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Kunming Biohome Technology Co. Ltd.

website:http://www.biohometech.com/

Contact:86-871-67428869

Address:kunming
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China

Relevant to this article

Behavior of 2-phenyl-2,3-dihydro-1H-1,3-phenalenediones in formylation by Vilsmeier - Haak procedure

Doi:10.1023/A:1020938601869
(2002)
Doi:10.1021/ja01142a027
(1952)
Chiral metal architectures in aminopyridinato complexes of zirconium

Doi:10.1039/b413023e
(2004)
The chemistry of thujone. V. Thujone as a chiral synthon for the preparation of sesquiterpenes. Synthesis of (+)-carissone

Doi:10.1139/v82-255
(1982)
The enhancement of xylose monomer and xylotriose degradation by inorganic salts in aqueous solutions at 180 °C

Doi:10.1016/j.carres.2006.07.017
(2006)
A direct intramolecular asymmetric catalytic aldol cyclodehydration of meso-3,4-disubstituted-1,6-dialdehydes

Doi:10.1016/j.tet.2004.10.034
(2005)

Article Doi