Synthesis in Solution of High Nuclearity Osmium Cluster Species: X-Ray Analysis of (1-)

DOI: 10.1039/c39820000419

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 419 - 421 (1982)

Update date:2022-09-26

Topics:

Authors:

Braga, Dario

Henrick, Kim

Johnson, Brian F. G.

Lewis, Jack

McPartlin, Mary

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000419

Reaction of Os3(CO)12 with KOH in isobutanol has given a range of high nuclearity cluster species based on up to ten osmium atoms; in the absence of base a new cluster hydrido-monoanion (1-) is produced which, on the basis of an X-ray analysis, has been shown to possess an unusual metal core geometry that cannot be explained by conventional skeletal electron counting procedures.

Full text of DOI:10.1039/c39820000419

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[N(P(C₆H₅)3)2]⁽¹⁺⁾*[Os₈H(CO)22]^(1-)=[N(P(C₆H₅)3)2][Os₈H(CO)22]

Cas No:82727-85-3

R&D Labs maybe for 82727-85-3

Shanghai Rich Chemicals Co., Ltd

website:http://www.richchemical.com

Contact:+86-21-20255798

Address:Pudong Shanghai,China
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
A-Chem Technologies Co.,Ltd.

Contact:+86-512-69561895

Address:No.111, Building A4, 218 Xinghu Street, Suzhou Industrial Park, P. R. China
Jewim Pharmaceutical (Shandong) Co., Ltd

Contact:+8615621883869

Address:山东省泰安市高新技术产业开发区配天门大街西首
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China

Relevant to this article

Doi:10.1021/ja01074a031
(1964)
A new synthetic approach to N,N′-disubstituted 1,n-alkanediamines

Doi:10.1081/SCC-100103257
(2001)
Isolation and characterization of a new 5-aminofurylthiazole from the catalytic reduction of 4-(5-nitro-2-furyl)thiazole

Doi:10.1248/cpb.33.5581
(1985)
A NOVEL CYCLODIMERIZATION OF 3-METHYL-3-BUTENENITRILE. AN EFFICIENT SYNTHESIS OF 4-CYANOISOPHORONE

Doi:10.1016/0040-4039(80)80206-1
(1980)
Regioselective Synthesis of 1-Sulfanyl- and 1-Selanylindolizines

Doi:10.1021/acs.joc.9b00871
(2019)
Studies on tertiary amine oxides. LXXVI. Reactions of aromatic N-oxides with 1,3-cyclohexanediones in the presence of acetic anhydride

Doi:10.1248/cpb.30.2326
(1982)

Article Doi