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Synthesis in Solution of High Nuclearity Osmium Cluster Species: X-Ray Analysis of (1-)

DOI: 10.1039/c39820000419

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 419 - 421 (1982)

Update date:2022-09-26

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Authors:

Braga, DarioBraga, Dario

Henrick, KimHenrick, Kim

Johnson, Brian F. G.Johnson, Brian F. G.

Lewis, JackLewis, Jack

McPartlin, MaryMcPartlin, Mary

et al.et al.

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Article abstract of DOI:10.1039/c39820000419

Reaction of Os3(CO)12 with KOH in isobutanol has given a range of high nuclearity cluster species based on up to ten osmium atoms; in the absence of base a new cluster hydrido-monoanion (1-) is produced which, on the basis of an X-ray analysis, has been shown to possess an unusual metal core geometry that cannot be explained by conventional skeletal electron counting procedures.

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Product name:[N(P(C6H5)3)2](1+)*[Os8H(CO)22](1-)=[N(P(C6H5)3)2][Os8H(CO)22]

Cas No:82727-85-3

82727-85-3

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