A Stereochemical Model of the Veratrum Alkaloids

DOI: 10.1021/jo00142a026

Source and publish data:

Journal of Organic Chemistry p. 4137 - 4145 (1982)

Update date:2022-08-03

Topics:

Authors:

Brambilla, R.

Friary, R.

Ganguly, A.

Puar, M. S.

Topliss, J. G.

et. al. et. al.

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Article abstract of DOI:10.1021/jo00142a026

A stereoselective synthesis begining from the tetracyclic isoxazolidine 3 gave an inactive model (2) of rings D-F of the hypotensive Veratrum alkaloids (1).Cleaving, N-demethylating, and epimerizing 3 gave the amino alcohol 5a.Diazotizing 5a afforded lact

Full text of DOI:10.1021/jo00142a026

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