STEREOCHEMICAL STUDIES-XXVIII. CONFORMATIONAL EQUILIBRIA OF 2-OCH3, 2-OCOCH3 AND 2-Br DERIVATIVES OF ω-SUBSTITUTED METHYLENECYCLOHEXANES

Article abstract of DOI:10.1016/S0040-4020(01)88686-5

The conformational equilibria of the titled compounds, 10-13, have been determined by ¹H NMR and analysed in terms of steric (A^(1,3) repulsion, 15) and electronic effects.The conformational equilibria of OMe and Br derivatives depend