CARBOCYCLIZATION BY HOMOLYTIC SUBSTITUTION (SH' PROCESS). A NEW ROUTE TO DIHYDROINDOLE OR DIHYDROBENZOFURAN

DOI: 10.1016/S0040-4039(00)87399-2

Source and publish data:

Tetrahedron Letters p. 2575 - 2576 (1982)

Update date:2022-08-16

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Authors:

Ueno, Yoshio

Chino, Kunitake

Okawara, Makoto

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Article abstract of DOI:10.1016/S0040-4039(00)87399-2

N-(4-Phenyltio-2-butenyl)-2-bromoaniline reacted with tributyltin hydride to give 3-vinyl-2,3-dihydroindole in 96percent yield via hitherto unknown intramolecular S_H' process, some other examples and remarkable dilution effect on these homolytic carbocyclizations were described.

Full text of DOI:10.1016/S0040-4039(00)87399-2

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