ALUMINIUM-CHLORIDE CATALYZED REACTION OF ALLYLIC SULFIDES WITH METHYL PROPIOLATE: A NOVEL ADDITION REACTION VIA AN IONIC SIGMATROPIC REARRANGEMENT

DOI: 10.1016/S0040-4039(00)87291-3

Source and publish data:

Tetrahedron Letters p. 2171 - 2174 (1982)

Update date:2022-07-30

Topics:

Authors:

Hayakawa, Kenji

Kamikawaji, Yoshimasa

Kanematsu, Ken

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Article abstract of DOI:10.1016/S0040-4039(00)87291-3

The aluminium-chloride catalyzed reaction of allylic sulfides with methyl propiolate resulted in the clean formation of novel 1:1 adducts via ionic <3.3> sigmatropic rearrangements.

Full text of DOI:10.1016/S0040-4039(00)87291-3

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