A Simple Preparation for (η6-Arene)(η4-cyclo-octa-1,5-diene)rhuthenium(0) Complexes and their Conversion into the Corresponding Arene-Dichlororuthenium(II) Complexes

DOI: 10.1039/DT9820001019

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1019 - 1022 (1982)

Update date:2022-08-05

Topics:

Authors:

Pertici, Paolo

Vitulli, Giovanni

Lazzaroni, Raffaello

Salvadori, Piero,

Barili, Pier Luigi

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Article abstract of DOI:10.1039/DT9820001019

A series of (η⁶-arene)(η⁴-cyclo-octa-1,5-diene)ruthenium(0) complexes have been readily prepared by reaction of (?⁴-cyclo-octa-1,5-diene)(η⁶-cyclo-octa-1,3,5-triene)rhuthenium(0) with arene compounds, under 1 atm H2.These complexes react with aqueous HCl to give in almost quantitative yield the corresponding (η⁶-arene)dichlororuthenium(II) complexes.

Full text of DOI:10.1039/DT9820001019

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