PROTONATION OF METAL-METAL BONDS IN HETEROBIMETALLIC COMPOUNDS LINKED BY A HETERODIFUNCTIONAL LIGAND

DOI: 10.1016/S0022-328X(00)99507-X

Source and publish data:

Journal of Organometallic Chemistry p. 245 - 248 (1983)

Update date:2022-08-05

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Authors:

Casey, Charles P.

Bullock, R. Morris

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Article abstract of DOI:10.1016/S0022-328X(00)99507-X

Addition of trifluoromethanesulfonic acid to the heterobimetallic compounds (I) and (II) results in protonation of the metal-metal bond to give cationic compounds with bridging hydrides (III and IV).Deprotonation of III and IV with triethylamine regenerates I and II in high yield.

Full text of DOI:10.1016/S0022-328X(00)99507-X

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