Trimethylsilyl Iodide Catalyzed Spirocyclization of Amines. Synthesis of Perhydrohistrionicotoxin

DOI: 10.1021/jo00145a057

Source and publish data:

Journal of Organic Chemistry p. 4820 - 4822 (1982)

Update date:2022-08-04

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Authors:

Godleski, Stephen A.

Heacock, Deborah J.

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Article abstract of DOI:10.1021/jo00145a057

A trimethylsilyl iodide catalyzed Michael reaction of an enone amine and a trimethylsilyl iodide catalyzed S_N2' spirocyclization of an allylic alcohol amine are the crucial reactions in two new syntheses of perhydrohistrionicotoxin.

Full text of DOI:10.1021/jo00145a057

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