Stabilization of 7-Phosphanorbornadienes by Complexation; X-Ray Crystal Structure of 2,3-Bis(methoxycarbonyl)-5,6-dimethyl-7-phenyl-7-phosphanorbornadiene(pentacarbonyl)chromium

DOI: 10.1039/c39820000667

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Journal of the Chemical Society. Chemical communications p. 667 - 668 (1982)

Update date:2022-08-04

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Authors:

Marinetti, Angela

Mathey, Francois

Fischer, Jean

Mitschler, Andre

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Article abstract of DOI:10.1039/c39820000667

The reaction of dimethyl acetylenedicarboxylate with LM(CO)5 complexes (L = 1-substituted-3,4-dimethylphosphole; M = Cr, Mo, W) provides an easy access to stable 7-phosphanorbornadiene complexes, the X-ray crystal structure of one of which is reported; th

Full text of DOI:10.1039/c39820000667

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