Tetrahedron Letters p. 3341 - 3344 (1982)
Update date:2022-08-03
Topics:
Liese, Thomas
Splettstaesser, Gisela
Meijere, Armin de
The perchlorovinylcarbene adducts of ethylene and propylene served as precursors to a wide spectrum of 1'-substituted cyclopropylacetylenes 4, 8 and 9, which are versatile polyfunctional molecules.E.g., the acetylenic ester 4c underwent cycloaddition to 1,3-dienes giving otherwise unaccessible compounds.
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