Regioselective Functionalization. β Substituent Effects on the Regioselectivity of Baeyer-Villiger Oxidations of 3-Substituted 2-Azabicyclooctan-5-ones (Isoquinuclidin-5-ones)

DOI: 10.1021/jo00148a002

Source and publish data:

Journal of Organic Chemistry p. 5239 - 5243 (1982)

Update date:2022-09-26

Topics:

Authors:

Krow, Grant R.

Johnson, Constance A.

Guare, James P.

Kubrak, Dennis

Henz, Kenneth J.

et al. et al.

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Article abstract of DOI:10.1021/jo00148a002

The regioselectivity of the Baeyer-Villiger oxidation of N-carboalkoxy-2-azabicyclo<2.2.2>octan-5-ones 1 has been found to vary markedly as a function of the identity and stereochemistry of the substituent at the 3-position and the choice of peracid oxida

Full text of DOI:10.1021/jo00148a002

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