Asymmetric synthesis of homopropargylic alcohols from aldehydes and allenyltri-n-butylstannane

DOI: 10.1016/S0040-4039(00)74397-8

Source and publish data:

Tetrahedron Letters p. 8323 - 8324 (1994)

Update date:2022-09-26

Topics:

Authors:

Keck, Gary E.

Krishnamurthy, Dhileepkumar

Chen, Xi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74397-8

The reaction of allenyltri-n-butylstannane with aldehydes and a chiral Lewis acid prepared from (R)-BINOL and Ti(O-i-Pr)₄ gives homopropargylic alcohols with 82 - > 99% ee

Full text of DOI:10.1016/S0040-4039(00)74397-8

Products guided by the article

Product name:(S)-(+)-1-(furan-2-yl)but-3-yn-1-ol

Cas No:83816-49-3

R&D Labs maybe for 83816-49-3

GM CHMICAL CO., LTD

Contact:0086-21-80264647

Address:RM 202, NO 1602 West Zhongshan Rd, Shanghai, China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town

Relevant to this article

Conjugate additions of a simple monosilylcopper reagent with use of the CuI-DMS complex: Stereoselectivities and a dramatic impact by DMS

Doi:10.1021/jo048269e
(2005)
Sur la reaction de l'iodure de trimethylsilyle avec les alcools acetyleniques

Doi:10.1016/S0040-4039(00)87672-8
(1982)
Total synthesis of (±)-3-deoxy-7,8-dihydromorphine, (±)-4-methoxy-N-methylmorphinan-6-one and 2,4-dioxygenated (±)-congeners

Doi:10.1002/hlca.19820650531
(1982)
ASYMMETRIC CONJUGATE ADDITION OF ZINCATES OR CUPRATES CONTAINING AN OPTICALLY ACTIVE AZAENOLATE OF erythro-ISOPROPYLIDENE-2-METHOXY-1,2-DIPHENYLAMINE TO 2-CYCLOALKENONES

Doi:10.1016/S0040-4039(01)91370-X
(1987)
New rare-earth metal acyl pyrazolonates: Synthesis, crystals structures, and luminescence properties

Doi:10.1134/S1070328414090024
(2014)
Doi:10.1007/BF00849431
()

Article Doi