Asymmetric synthesis of homopropargylic alcohols from aldehydes and allenyltri-n-butylstannane

DOI: 10.1016/S0040-4039(00)74397-8

Source and publish data:

Tetrahedron Letters p. 8323 - 8324 (1994)

Update date:2022-09-26

Topics:

Authors:

Keck, Gary E.

Krishnamurthy, Dhileepkumar

Chen, Xi

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Article abstract of DOI:10.1016/S0040-4039(00)74397-8

The reaction of allenyltri-n-butylstannane with aldehydes and a chiral Lewis acid prepared from (R)-BINOL and Ti(O-i-Pr)₄ gives homopropargylic alcohols with 82 - > 99% ee

Full text of DOI:10.1016/S0040-4039(00)74397-8

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