Synthesis of Adamantane Derivatives. 60. Stereospecific Synthesis of 2,4 Amino Alcohol Derivatives of Noradamantane, Protoadamantane, and Adamantane via Bicycloalkenylnitrones

DOI: 10.1021/jo00148a005

Source and publish data:

Journal of Organic Chemistry p. 5250 - 5255 (1982)

Update date:2022-09-26

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Authors:

Sasaki, Tadashi

Eguchi, Shoji

Suzuki, Takanori

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Article abstract of DOI:10.1021/jo00148a005

The intramolecular 1,3-dipolar cycloadditions of C-bicycloalkenylnitrones 3, 9, and 17 generated in situ from the aldehydes 1, 8, and 16 and hydroxylamines proceeded smoothly at 25-80 deg C, affording 2,4-(epoxyimino)-noradamantane (4), 2,4-(epoxyimino)pr

Full text of DOI:10.1021/jo00148a005

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