Bulletin of the Chemical Society of Japan p. 2781 - 2790 (1984)
Update date:2022-08-04
Topics:
Furuta, Kyoji
Ikeda, Yoshihiko
Meguriya, Noriyuki
Ikeda, Nobuo
Yamamoto, Hisashi
<3-(Ethylthio)allyl>titanium reagent generated easily from allyl ethyl sulfides condensed with aldehydes to give erythro-β-hydroxy sulfides in highly regio- and stereoselective manner.In contrast, crotyl ethyl sulfide reacted with aldehydes affording δ-hydroxy vinyl sulfide exclusively.The substitution pattern of the starting sulfide can have a pronounced effect on the selectivity in this condensation reaction, erythro-β-Hydroxy sulfide obtained was transfromed stereoselectively to the trans-vinyloxirane or 1,3-alkadiene.
View MoreNanjing HuiBaiShi Biotechnology Co.,Ltd.
Contact:+86 (25)58745219
Address:No.606 Ningliu Road,LiuHe District.
Contact:86-571-61063068
Address:LINAN
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang,Hebei, China
Huangshan Violet Biological Technology Co., Ltd
Contact:+86-559-2335676
Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Contact:0512-63006287
Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
Doi:10.1016/S0022-328X(00)99710-9
(1986)Doi:10.1021/ja00342a023
(1983)Doi:10.1021/ja00343a024
(1983)Doi:10.1002/jhet.5570190322
(1982)Doi:10.1021/ja00343a035
(1983)Doi:10.1055/s-1982-30019
(1982)