Bulletin of the Chemical Society of Japan p. 2781 - 2790 (1984)
Update date:2022-08-04
Topics:
Furuta, Kyoji
Ikeda, Yoshihiko
Meguriya, Noriyuki
Ikeda, Nobuo
Yamamoto, Hisashi
<3-(Ethylthio)allyl>titanium reagent generated easily from allyl ethyl sulfides condensed with aldehydes to give erythro-β-hydroxy sulfides in highly regio- and stereoselective manner.In contrast, crotyl ethyl sulfide reacted with aldehydes affording δ-hydroxy vinyl sulfide exclusively.The substitution pattern of the starting sulfide can have a pronounced effect on the selectivity in this condensation reaction, erythro-β-Hydroxy sulfide obtained was transfromed stereoselectively to the trans-vinyloxirane or 1,3-alkadiene.
View MoreWuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Contact:+86-533-3112891
Address:zibo
Suzhou CarbonWell Pharma-Tech Co., Ltd
Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602
Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
Shijiazhuang Yunxuan Im&Export Co.,Ltd.
Contact:+86-311-83037514
Address:No.6 Hongbin Road
Hangzhou yi lu biont technology Co., LTD
Contact:+86-571-88152630
Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Doi:10.1016/S0022-328X(00)99710-9
(1986)Doi:10.1021/ja00342a023
(1983)Doi:10.1021/ja00343a024
(1983)Doi:10.1002/jhet.5570190322
(1982)Doi:10.1021/ja00343a035
(1983)Doi:10.1055/s-1982-30019
(1982)
