Journal of Organic Chemistry p. 570 - 574 (1983)
Update date:2022-09-26
Topics:
Gnanadoss, Lalitha Mary
Radha, N.
A series of new bicyclic anions containing the bicyclo<3.3.1>nonane skeleton have been prepared from 1,3,5-trinitrobenzene and carbanions derived from substituted acetoacetanilides.The condensation-cyclizations are initiated by triethylamine.A mechanistic picture for the cyclization is shown as proceeding through a delocalized carbanion intermediate.
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Doi:10.1039/b909803h
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(1983)
